Space as a spectroscopic laboratory: High-resolution spectroscopy of the [$^{13}$C II] hyperfine structure with SOFIA/upGREAT

The [$^{12}$C II] emission at 158 $\mu$m is a key cooling line of the interstellar medium and traces gas kinematics in spectrally resolved observations.

Its spectral profile is often modified by optical depth effects.

The intrinsic line shape can be reconstructed by comparison with emission from the less abundant $^{13}$C isotope.

Due to the additional neutron spin, [$^{13}$C II] emission splits into three hyperfine structure (hfs) transitions.

Laboratory measurements have provided the centroid frequency and the strongest component ($F=2-1$); the two weaker components ($F=1-0$ and $F=1-1$) have been inferred only from quantum-mechanical calculations.

The magnetic-dipole hfs constants, from which the transition frequencies follow, have not been measured experimentally.

The high spectral resolution of observations with the upgraded German Receiver for Astronomy at Terahertz Frequencies (upGREAT) on board SOFIA enabled simultaneous detection of all three hfs transitions.

From these astronomical data we determine, for the first time, the magnetic-dipole hfs constants $A_{1/2}^{\rm hf} = 810.71(11)$ MHz and $A_{3/2}^{\rm hf} = 162.18(5)$ MHz of the [$^{13}$C II] $2s^2\,2p\,{}^2P^\circ$ ground term.

Combined with the laboratory centroid frequency, this yields the rest frequencies of all three hfs lines.

Using [$^{12}$C II] as a reference, we also improve the precision of the [$^{13}$C II] centroid frequency.

This work shows that spectrally resolved astronomical observations can constrain fundamental atomic properties, with hfs precision rivaling laboratory measurements.

The approach extends to other atomic and molecular transitions where laboratory data are difficult to obtain.