Large spin splitting at ferromagnetic surfaces of bulk antiferromagnets

Condensed Matter > Materials Science [Submitted on 18 Jun 2026] Title:Large spin splitting at ferromagnetic surfaces of bulk antiferromagnets View PDF HTML (experimental)Abstract:We use density functional theory and model Hamiltonians to reveal large spin splitting of bands localized at low-symmetry, ferromagnetic surfaces of bulk antiferromagnets (AFMs). There is great interest in finding new material platforms combining the robustness and ultrafast dynamics of AFMs with large, functional spin splitting which is often restricted to ferromagnets. Here, we show that a subset of AFM surfaces which have symmetry-allowed magnetization can host large spin splitting via bulk degeneracy lifting of sublattice-resolved exchange splittings. Using model Hamiltonians, we show that the spin splitting is maximized for two ferromagnetic surface motifs: terminations with single uncompensated magnetic sublattices, and two-sublattice surfaces whose sublattices are magnetically and electronically compensated in the bulk, but acquire distinct crystal field environments via surface truncation. The latter case can yield FM-like spin splitting magnitudes while also having vanishingly small uncompensated magnetization. In contrast, when surface magnetization arises from relativistic canting on symmetry-connected sublattices, the spin splitting is expected to be small. We confirm these predictions with first-principles calculations of $\mathrm{Cr_2O_3}$ and $\mathrm{FeF_2}$, finding splittings from $\sim10\mathrm{meV}$-$\sim1\mathrm{eV}$ depending on the surface in question. Our findings point to intrinsic surface symmetry breaking as a route to large, functional spin splitting in an expanded range of AFM materials. Submission history From: William Schaarman [view email][v1] Thu, 18 Jun 2026 12:49:05 UTC (11,221 KB) Current browse context: cond-mat.mtrl-sci Change to browse by: References & Citations Loading... Bibliographic and Citation Tools Bibliographic Explorer (What is the Explorer?) Connected Papers (What is Connected Papers?) Litmaps (What is Litmaps?) scite Smart Citations (What are Smart Citations?) Code, Data and Media Associated with this Article alphaXiv (What is alphaXiv?) CatalyzeX Code Finder for Papers (What is CatalyzeX?) DagsHub (What is DagsHub?) Gotit.pub (What is GotitPub?) Hugging Face (What is Huggingface?) ScienceCast (What is ScienceCast?) Demos Recommenders and Search Tools Influence Flower (What are Influence Flowers?) CORE Recommender (What is CORE?) IArxiv Recommender (What is IArxiv?) arXivLabs: experimental projects with community collaborators arXivLabs is a framework that allows collaborators to develop and share new arXiv features directly on our website. Both individuals and organizations that work with arXivLabs have embraced and accepted our values of openness, community, excellence, and user data privacy. arXiv is committed to these values and only works with partners that adhere to them. Have an idea for a project that will add value for arXiv's community? Learn more about arXivLabs.