Shear-Induced Electrophoretic Migration Perpendicular to the Electric Field

Condensed Matter > Soft Condensed Matter [Submitted on 18 Jun 2026] Title:Shear-Induced Electrophoretic Migration Perpendicular to the Electric Field View PDF HTML (experimental)Abstract:Recent experiments combining electrophoresis with pressure-driven flows in microchannels have revealed that microparticles undergo lateral migration perpendicular to the applied electric field. Although fluid inertia has been proposed as a possible explanation, inertial effects are negligibly small in these regimes, leaving the underlying physical mechanism an open question. In this study, we address these observations by extending previous theoretical work on concentration polarization,i.e., the external-field-induced modification of the ionic concentration field surrounding a dielectric object. We consider a dielectric particle with surface conductance subjected simultaneously to an external electric field and a shear flow. We show that the shear flow breaks the symmetry of the ionic concentration around the particle in the direction perpendicular to the applied field, thereby driving lateral migration. We demonstrate that the resulting migration velocity comprises two distinct contributions: an electrophoretic and a diffusiophoretic component. Our theory yields an explicit expression for the velocity magnitude as a function of the zeta potential and the Dukhin number, predicting typical speeds on the order of $\mathrm{\mu}$m/s for representative experimental parameters. Notably, the model also predicts a reversal in the migration direction for Dukhin numbers of order unity. Submission history From: Pablo Garcia-Sanchez [view email][v1] Thu, 18 Jun 2026 08:10:15 UTC (1,141 KB) Current browse context: cond-mat.soft Change to browse by: References & Citations Loading... Bibliographic and Citation Tools Bibliographic Explorer (What is the Explorer?) Connected Papers (What is Connected Papers?) Litmaps (What is Litmaps?) scite Smart Citations (What are Smart Citations?) Code, Data and Media Associated with this Article alphaXiv (What is alphaXiv?) CatalyzeX Code Finder for Papers (What is CatalyzeX?) DagsHub (What is DagsHub?) Gotit.pub (What is GotitPub?) Hugging Face (What is Huggingface?) ScienceCast (What is ScienceCast?) Demos Recommenders and Search Tools Influence Flower (What are Influence Flowers?) CORE Recommender (What is CORE?) IArxiv Recommender (What is IArxiv?) arXivLabs: experimental projects with community collaborators arXivLabs is a framework that allows collaborators to develop and share new arXiv features directly on our website. Both individuals and organizations that work with arXivLabs have embraced and accepted our values of openness, community, excellence, and user data privacy. arXiv is committed to these values and only works with partners that adhere to them. Have an idea for a project that will add value for arXiv's community? Learn more about arXivLabs.