Statistics of non-conserved observables in Lindblad master equations

We study the dynamics of observables that are conserved under the Hamiltonian evolution of a closed quantum system, but cease to be conserved when the system is coupled to a Markovian environment and described by a Lindblad master equation.

Starting from the adjoint Lindblad equation, we derive elementary expressions for the time derivatives of the expectation value and second moment of an observable $O$, with particular emphasis on the case $[H,O]=0$ but $\mathcal L^\dagger(O)\neq 0$.

These formulae provide a direct assessment of how collapse operators break Hamiltonian conservation laws and generate fluctuations of formerly conserved quantities.

The discussion is illustrated by analytic examples: one-qubit amplitude damping, a two-qubit excitation-number model, a momentum-diffusion model in which the mean is conserved while the variance grows, and the Jaynes-Cummings model.

The latter also shows the complementary case of a reservoir coupled through a conserved quantity, where dephasing can occur without changing the statistics of that quantity.

We finally comment on the relation between Lindblad source terms and idealized wave-function reduction models in which local conservation may hold only statistically.