Small Matrices with Large Inverses: Unimodular $4 \times 4$ Cases

How close to singularity can an $n \times n$ unimodular matrix be?

For ternary cases as $n$ increases, exact expressions are unlikely, but upon fixing $n=4$ and assessing $(2k+1)$-ary cases as $k$ increases, we make significant progress; similarly for $(k+1)$-ary cases of $4\times 4$ nonnegative unimodular matrices.